Lightly grease the interior of a 6-quart slow cooker crock with non-stick spray or olive oil.
Distribute the sliced bell peppers and onions evenly across the bottom of the crock.
Optional: In a large skillet over medium-high heat, brown the sausage links for 2-3 minutes per side to develop color; transfer to the crock and place on top of the vegetables.
In a mixing bowl, combine the marinara sauce, minced garlic, dried oregano, red pepper flakes, salt, and black pepper.
Pour the seasoned sauce mixture over the sausages and vegetables.
Cover the slow cooker and cook on the Low setting for 6 hours (or High for 3 to 4 hours).
Verify that the sausages have reached a minimum internal temperature of 160°F (71°C).
Stir the mixture gently to incorporate the rendered juices and serve on toasted hoagie rolls or over cooked pasta.